PRELIMINARY ASSESSMENT OF AGRICULTURE INFLUENCE ON HEAVY METAL CONTENT IN BOTTOM SEDIMENTS OF SMALL WATER RESERVOIRS AND IN RUSHES

The main purpose of the paper was to determine the influence of catchment management on the bottom sediments quality of small water reservoirs as well as to determine toxic metal content in rushes. Samples of bottom sediments were collected in winter 2013 year, form 4 sediment layers (0-5, 5-10, 10-20 and 20-30 cm) at three points along the body of water. The 48 samples were collected. Soil material was prepared according to the procedures used in soil science, the analysis was performed for the fraction with a particle diameter of less than 1 mm. Plant samples from single species aggregations were randomly cut from 5 to 10 locations of 20-50 m2 area. From these samples the average composite sample was prepared. The total content of such elements as Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, Zn was determined by atomic absorption spectrometry (using the Thermo Scientific iCE 3000 series spectrometer) after prior digestion in the mixture (5:1) of concentrated acids HNO3 (65%) and HClO4 (60%). Total Hg content was determined by the AMA 254 analyzer. Between the small water reservoirs adjacent to the areas where organic farming is used, and the reservoirs adjacent to the areas with mineral fertilization ...

ASSESSMENT OF HEAVY METAL POLLUTION IN BOTTOM SEDIMENTS OF SMALL WATER RESERVOIRS WITH DIFFERENT CATCHEMENT MANAGEMENT

The main purpose of this work was to determine the degree of negative impact of heavy metals accumulated in the water sediments to aquatic organisms. Samples of sediments were collected in winter 2013, from 4 layers of sediment (0-5, 5-10, 10-20 and 20-30 cm) at three points along the water reservoir. Sediments were prepared for analysis in accordance with the procedures applied in soil science. The analysis was carried out for the fraction with a particle diameter less than 1 mm. The total content of such elements as Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb and Zn, was determined by atomic absorption spectrometry (using the Thermo Scientific iCE 3000 series spectrometer) after digestion in a mixture (5:1) of concentrated acid HNO3 (65 %) and HClO4 (60%). The total Hg content was obtained by using the AMA 254 analyzer. Only the lead content in the analyzed samples of bottom sediments exceeded the contamination value given by polish law (the Regulation of the Minister of Environment). According to the classification of PGI samples of sediments are classified mainly as medium polluted sediments (Class II), with the exception of zinc and lead concentrations (Class III). Due to the value of the indicator ...